|
|
UDP-glucose + validoxylamine_A <=> validamycin_A + UDP + H+
|
2.4.1.338
validoxylamine A glucosyltransferase
|
–
|
| |
BRENDA:
BR51706
KEGG:
R11241
MetaCyc:
RXN-9148
|
|
|
|
1,7-Diphospho-1-epi-valienol + NTP <=> NDP-1-epi-valienol_7-phosphate + diphosphate
|
2.7.7.91
valienol-1-phosphate guanylyltransferase
|
–
|
| |
KEGG:
R11246
|
|
|
|
dTDP-glucose <=> H2O + dTDP-4-dehydro-6-deoxy-D-glucose
|
4.2.1.46
dTDP-glucose 4,6-dehydratase
4.2.1.76
UDP-glucose 4,6-dehydratase
|
–
–
|
| |
BRENDA:
BR425
KEGG:
R06513
MetaCyc:
DTDPGLUCDEHYDRAT-RXN
SABIO-RK:
2648;
8948
|
|
|
|
valienone_7-phosphate <=> validone_7-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11236
|
|
|
|
2-Amino-5-epi-valiolone <=> 2-Aminovalienone
|
not assigned
|
–
|
| |
KEGG:
R11252
|
|
|
|
1-epi-Valienol_1-phosphate + NTP <=> NDP-1-epi-valienol + diphosphate
|
2.7.7.91
valienol-1-phosphate guanylyltransferase
|
–
|
| |
KEGG:
R11237
|
|
|
|
dTTP + alpha-D-glucose_1-phosphate + H+ <=> dTDP-glucose + diphosphate
|
2.7.7.24
glucose-1-phosphate thymidylyltransferase
2.7.7.64
UTP-monosaccharide-1-phosphate uridylyltransferase
2.7.7.9
UTP---glucose-1-phosphate uridylyltransferase
|
–
–
–
|
| |
BRENDA:
BR47871;
BS426212
KEGG:
R02328
MetaCyc:
DTDPGLUCOSEPP-RXN
SABIO-RK:
2281;
8935
|
|
|
|
5-epi-Valiolol_7-phosphate <=> 1-epi-valienol_7-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11244
|
|
|
|
dTDP-acarviose-7-phosphate <=> acarbose_7'''-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11248
|
|
|
|
valienol_7-phosphate <=> valienol_1-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11499
MetaCyc:
RXN-17383
|
|
|
|
1-epi-valienol_7-phosphate <=> 1-epi-Valienol_1-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11249
|
|
|
|
GDP-valienol + validamine_7-phosphate <=> validoxylamine_A_7''-phosphate + GDP + H+
|
2.5.1.135
validamine 7-phosphate valienyltransferase
|
–
|
| |
BRENDA:
BR51891
KEGG:
R11497
MetaCyc:
RXN-17379
|
|
|
|
5-epi-valiolone <=> valienone + H2O
|
4.2.1
|
–
|
| |
KEGG:
R11233
MetaCyc:
RXN-9142
|
|
|
|
validamycin_A + 2-oxoglutarate + O2 <=> validamycin_B + succinate + CO2
|
1.14.11.52
validamycin A dioxygenase
|
–
|
| |
BRENDA:
BR51692
KEGG:
R11340
MetaCyc:
RXN-17381
|
|
|
|
valienone + ATP <=> H+ + valienone_7-phosphate + ADP
|
2.7.1.214
C7-cyclitol 7-kinase
|
–
|
| |
BRENDA:
BR51758
KEGG:
R11234
MetaCyc:
RXN-9144
|
|
|
|
Salbostatin_6''-phosphate + H2O <=> Salbostatin + phosphate
|
3.1.3
|
–
|
| |
KEGG:
R11251
|
|
|
|
ATP + acarbose <=> ADP + acarbose_7'''-phosphate + H+
|
2.7.1.187
acarbose 7IV-phosphotransferase
|
–
|
| |
BRENDA:
BR51233
KEGG:
R11184
MetaCyc:
RXN-16280
|
|
|
|
ATP + 2-epi-5-epi-valiolone <=> ADP + 2-epi-5-epi-valiolone_7-phosphate + H+
|
2.7.1.188
2-epi-5-epi-valiolone 7-kinase
|
–
|
| |
BRENDA:
BR51232
KEGG:
R11185
MetaCyc:
RXN-16279
|
|
|
|
5-epi-valiolone <=> 2-Keto-5-epi-valiolone
|
not assigned
|
–
|
| |
KEGG:
R11253
|
|
|
|
GTP + valienol_1-phosphate + H+ <=> GDP-valienol + diphosphate
|
2.7.7.91
valienol-1-phosphate guanylyltransferase
|
–
|
| |
BRENDA:
BR51761
KEGG:
R11402
MetaCyc:
RXN-17377
|
|
|
|
2-Keto-5-epi-valiolone <=> 2-Amino-5-epi-valiolone
|
not assigned
|
–
|
| |
KEGG:
R11254
|
|
|
|
5-epi-valiolone_7-phosphate + NADH + H+ <=> 5-epi-Valiolol_7-phosphate + NAD+
|
1.1.1
|
–
|
| |
KEGG:
R11243
|
|
|
|
valienone_7-phosphate <=> valienol_7-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11498
|
|
|
|
alpha-D-sedoheptulopyranose_7-phosphate <=> 2-epi-5-epi-valiolone + phosphate
|
4.2.3.152
2-epi-5-epi-valiolone synthase
|
–
|
| |
BRENDA:
BR51246
KEGG:
R10937
MetaCyc:
RXN-9140
|
|
|
|
Cetoniacytone_B <=> Cetoniacytone_A
|
not assigned
|
–
|
| |
KEGG:
R11255
|
|
|
|
2-oxoglutarate + dTDP-4-amino-4,6-dideoxy-alpha-D-glucopyranose <=> L-glutamate + dTDP-4-dehydro-6-deoxy-D-glucose
|
2.6.1.33
dTDP-4-amino-4,6-dideoxy-D-glucose transaminase
2.6.1.B6
|
–
–
|
| |
BRENDA:
BR47685
KEGG:
R02773
MetaCyc:
2.6.1.33-RXN
|
|
|
|
NDP-1-epi-valienol_7-phosphate + dTDP-4-amino-4,6-dideoxy-alpha-D-glucopyranose <=> dTDP-acarviose-7-phosphate
|
2.4
|
–
|
| |
KEGG:
R11247
|
|
|
|
NDP-1-epi-valienol + 2-Amino-1,5-anhydro-2-deoxyglucitol <=> Salbostatin_6''-phosphate + NDP
|
2.5.1.135
validamine 7-phosphate valienyltransferase
|
–
|
| |
KEGG:
R11250
|
|
|
|
validoxylamine_A_7''-phosphate + H2O <=> validoxylamine_A + phosphate
|
3.1.3.101
validoxylamine A 7'-phosphate phosphatase
|
–
|
| |
BRENDA:
BR51715
KEGG:
R11240
MetaCyc:
RXN-17380
|
|
|
|
2-epi-5-epi-valiolone_7-phosphate <=> 5-epi-valiolone_7-phosphate
|
5.1.3.35
2-epi-5-epi-valiolone 7-phosphate 2-epimerase
|
–
|
| |
BRENDA:
BR51426
KEGG:
R11081
MetaCyc:
RXN-16712
|
|
|
|
1-epi-valienol_7-phosphate <=> 1,7-Diphospho-1-epi-valienol
|
not assigned
|
–
|
| |
KEGG:
R11245
|
|
|
|
acarbose_7'''-phosphate <=> acarbose
|
not assigned
|
–
|
| |
KEGG:
R11305
|
|
|
|
validone_7-phosphate <=> validamine_7-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11238
|
|
|
|
2-epi-5-epi-valiolone <=> 5-epi-valiolone
|
5.1.3.33
2-epi-5-epi-valiolone epimerase
|
–
|
| |
BRENDA:
BR51250
KEGG:
R11079
MetaCyc:
RXN-9141
|
|
|
|
valienone_7-phosphate <=> 1-epi-valienol_7-phosphate
|
not assigned
|
–
|
| |
KEGG:
R11235
|
|
